Journal of Organometallic Chemistry

Synthesis and reactions of 1-substituted 3, 3-dimethylbenzo [d]-1, 3-azasilolines

T Aoyama, Y Sato, H Shirai

文献索引：Aoyama,T. et al. Journal of Organometallic Chemistry, 1976 , vol. 118, p. 1 - 6

全文：HTML全文

被引用次数: 8

摘要

Abstract 1-Substituted 3, 3-dimethylbenzo [d]-1, 3-azasilolines (III) were synthesized by intramolecular cyclization of the corresponding (3-chlorophenyl)(N-substituted aminomethyl) dimethylsilanes (II) by the use of phenyllithium. Reaction of III with benzyne generated from o-fluorobromobenzene and n-butyllithium gave 1-phenyl-2-substituted-3, 3-dimethylbenzo [d]-1, 3-azasilolines (VIII).