Journal of Organometallic Chemistry

Synthesis and reactions of 1-substituted 3, 3-dimethylbenzo [d]-1, 3-azasilolines

T Aoyama, Y Sato, H Shirai

Index: Aoyama,T. et al. Journal of Organometallic Chemistry, 1976 , vol. 118, p. 1 - 6

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Citation Number: 8

Abstract

Abstract 1-Substituted 3, 3-dimethylbenzo [d]-1, 3-azasilolines (III) were synthesized by intramolecular cyclization of the corresponding (3-chlorophenyl)(N-substituted aminomethyl) dimethylsilanes (II) by the use of phenyllithium. Reaction of III with benzyne generated from o-fluorobromobenzene and n-butyllithium gave 1-phenyl-2-substituted-3, 3-dimethylbenzo [d]-1, 3-azasilolines (VIII).