Photochemical 2+ 2 cycloaddition of arenecarboxylic acid esters to furans and 1, 3-dienes. 2+ 2 Cycloreversion of oxetanes to dienol esters and ketones
TS Cantrell, AC Allen, H Ziffer
文献索引:Cantrell, Thomas S.; Allen, Andrew C.; Ziffer, Herman Journal of Organic Chemistry, 1989 , vol. 54, # 1 p. 140 - 145
Methyl benzoate and other simple arenecarboxylic acid esters have been found to undergo 2+ 2 photochemical cycloaddition at the carbonyl group to furans and certain 1, 3-dienes. These additions afford mixtures of oxetanes and their 2+ 2 cycloreversion products: 4-aryl-4- alkoxy-l, 3-butadienyl formates and acetates (from furan oxetanes) and dienyl aldehydes and ketones (from cyclic 1, 3-dienes).