Journal of Organometallic Chemistry

Zur Umsetzung von Bis (alkinyl)-Titanocenen mit Übergangsmetall-Verbindungen von Cu (II), Pd (II), Pt (II), Fe (III) und Au (III)

W Frosch, S Back, K Köhler, H Lang

文献索引：Frosch; Back; Koehler; Lang Journal of Organometallic Chemistry, 2000 , vol. 601, # 2 p. 226 - 232

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被引用次数: 22

摘要

The reaction behaviour of the bis (alkynyl) titanocenes [Ti](C CR1)(C CR2){[Ti]=(η5- C5H4SiMe3) 2Ti; 1: R1= R2= Fc, Fc=(η5-C5H4) Fe (η5-C5H5); 5a: R1= R2= SiMe3; 5b: R1= R2= C6H5; 5c: R1= SiMe3, R2= C6H5} towards MX2 (M= Pd, Pt; X= Cl; M= Cu; X= Cl, Br, OAc, acac) and MCl3 (M= Fe, Au) is described. All reactions are dominated by redox processes. Generally, the reaction of 1 or 5a–5c with AuCl3 or MCl2 (M= Cu, Pd, Pt) ...