前往化源商城

Conformation Dependent Cyclizations of 1, 3, 3, 5-Tetraphenylpentane-1, 5-dione

…, J Novotný, B Kratochvíl, M Schwarz…

文献索引:Sebek, Pavel; Novotny, Jiri; Kratochvil, Bohumil; Schwarz, Marian; Kuthan, Josef Collection of Czechoslovak Chemical Communications, 1992 , vol. 57, # 11 p. 2383 - 2399

全文:HTML全文

被引用次数: 1

摘要

Abstract The molecular and crystal structure of 1, 3, 3, 5-tetraphenylpentane-1, 5-dione (I) obtained from direct methods and anisotropically refined by the least-squares method shows that the two 3, 3-phenyl groups force the molecule into a conformation suitable for formation of cyclic products and intermediates. Compound I crystallizes in P1 group with lattice parameters a= 8.444 (1), b= 10.195 (2), c= 14.618 (2) Å, α= 75.52 (2), β= 73.22 (1), γ= ...