Journal of the American Chemical Society

Polystyrene-bearing cyclopentadienyl metal catalysts: copolymerization of a styrene monomer containing cyclopentadiene synthons

A Sekiya, JK Stille

文献索引：Sekiya, Akira; Stille, J.K. Journal of the American Chemical Society, 1981 , vol. 103, # 17 p. 5096 - 5100

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被引用次数: 27

摘要

Abstract: The reaction of pstyrylmagnesium bromide with norbomenone gave syn-and anti-7- hydroxy-7-(p-styryl) norborn-2-ene (6) which could be converted to either the syn-and anti-7- methoxy derivative (8) or anti-7-chloro-7-@-styryl) norborn-2-ene (7). Both styryl monomers 7 and 8 were copolymerized with styrene and divinyl benzene to give polymers (9) containing 10 mol% of 7-substituted norbornyl derivatives. Treatment of the 7-chloro ...