Regulation of molecular conformation of chiral tripodal structures by calcium-cation binding

I Dayan, J Libman, A Shanzer, CE Felder…

文献索引：Dayan, Izac; Libman, Jacqueline; Shanzer, Abraham; Felder, Clifford E.; Lifson, Shneior Journal of the American Chemical Society, 1991 , vol. 113, # 9 p. 3431 - 3439

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被引用次数: 23

摘要

Abstract Chiral ligands are introduced whose conformations may be regulated by the presence of Ca2+ ions. These compounds are assembled from two types of C3-symmetric molecules as anchors (type 1 and type 2) and extended by chiral peptide residues. Their ion- binding properties are examined by a combination of experimental and theoretical tools (empirical force field (EFF) calculations). The calculations provide a conceptual framework ...