A new method for converting oxiranes to allylic alcohols by an organosilicon reagent

S Murata, M Suzuki, R Noyori

文献索引：Murata,S. et al. Journal of the American Chemical Society, 1979 , vol. 101, p. 2738 - 2739

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被引用次数: 88

摘要

(4) RB Woodward and R. Hoffmann," The Conservation of Orbital Symmetry." Verlag Chemie, Weinheim/Bergstr., Germany, 1971.(5) Commonly, formatiwr of loose triplet diradicals competes with the formation of syrnmetry-allowed triplet complexes. The reason is that the stabilization gained in the symmetryallowed geometry may not always be sufficient to override the overlap repulsion (exchange repulsion of the identical-spin electrons) ...