Synthesis and characterization of a branched-chain hexacarbene in a tridecet ground state. An approach to superparamagnetic polycarbenes

…, K Inoue, H Iwamura, T Fujioka, Y Sawaki

文献索引：Nakamura, Nobuo; Inoue, Katsuya; Iwamura, Hiizu; Fujioka, Toshio; Sawaki, Yasuhiko Journal of the American Chemical Society, 1992 , vol. 114, # 4 p. 1484 - 1485

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被引用次数: 86

摘要

S. nI3 1 2 sional. In order to realize the long-range order at finite temperatures, increasing the dimension of the aligned spins is imperative. This can be achieved either by imposing the proper stacking orientation and therefore magnetic interaction between the molecular chains of 1 as in crystalsS or by increasing the dimension of 1 itself. We have now introduced a branched-chain pseudo-two-dimensional structure 2 to achieve the latter ...