Tetrahedron

Carbon-carbon bond formation employing organoiron reagents: Syntheses of lavandulol and red scale pheromone

J Celebuski, M Rosenblum

文献索引：Celebuski, J.; Rosenblum, M. Tetrahedron, 1985 , vol. 41, # 24 p. 5741 - 5746

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被引用次数: 20

摘要

Some aspects of the chemistry of (η1-allyl) Fp complexes [Fp= η5-C5H5Fe (CO) 2] are briefly reviewed, especially the means available for their elaboration. The range of electrophiles which react with (η1-allyl) Fp complexes has been enlarged to include allyl iodides. Two examples of this reaction are given, the first leading to lavandulol 9, the second providing a short synthesis of the red scale pheromone (R, S-15).