Tetrahedron letters

A simple, efficient, and highly selective method for the iodination of alcohols using ZrCl 4/NaI

H Firouzabadi, N Iranpoor, M Jafarpour

文献索引：Firouzabadi, Habib; Iranpoor, Nasser; Jafarpour, Maasoumeh Tetrahedron Letters, 2004 , vol. 45, # 40 p. 7451 - 7454

全文：HTML全文

被引用次数: 48

摘要

To perform iodination of hydroxyl groups, several methods have been described using a variety of reagent systems such as BF 3 –Et 2 O/NaI, 7 P 4 /I 2 , 8 Cl 2 SO–DMF/KI, 9 MgI 2 , 10 HI, 11 ClSiMe 3 /NaI, 12 R 3 PI 2 –Et 2 O, or C 6 H 6 /HMPA, 13 CeCl 3 ·7H 2 O/NaI, 14 PPh 3 /DDQ/R 4 N + X − , 15 KI/BF 3 ·Et 2 O, 16 PPh 3 /DEAD/LiI, 17 and gas-phase reactions using KI in the presence of phase-transfer catalysts, 18 and/or I 2 /petroleum ether. 19 NaI/ ...