Preparation of Allyl and Vinyl Silanes by the Palladium??Catalyzed Silylation of Terminal Olefins: A Silyl??Heck Reaction

…, DT Ahneman, KA Johnson, DA Watson

文献索引：McAtee, Jesse R.; Martin, Sara E. S.; Ahneman, Derek T.; Johnson, Keywan A.; Watson, Donald A. Angewandte Chemie - International Edition, 2012 , vol. 51, # 15 p. 3663 - 3667

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被引用次数: 41

摘要

Allyl and vinyl silanes are indispensable nucleophiles in organic synthesis.[1] Notable applications include Hiyama cross-coupling reactions [2] and Hosomi-Sakurai-type allylation and crotylation reactions,[3] along with many others.[1c] Numerous methods are known for the preparation of both allyl and vinyl silanes.[4, 5] However, limitations exist with many of the current protocols, which often makes the synthesis of unsaturated organosilanes ...