Tetrahedron

Reaction pathways of zirconocene-catalyzed silylation of alkenes with chlorosilanes

J Terao, Y Jin, K Torii, N Kambe

文献索引：Terao, Jun; Jin, Yingshi; Torii, Kazushi; Kambe, Nobuaki Tetrahedron, 2004 , vol. 60, # 6 p. 1301 - 1308

被引用次数: 15

摘要

Reaction pathways as well as stereochemistries and stoichiometries of zirconocene- catalyzed silylation of olefins with chlorosilanes in the presence of nBuMgCl were studied and discussed in detail. Rate determining steps were examined by kinetic studies and labeling experiments.

~76%

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