Rate constants for abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals over the temperature range 650-770 K

HX Zhang, SI Ahonkhai…

文献索引：Zhang, H.-X.; Ahonkhai, S. I.; Back, M. H. Canadian Journal of Chemistry, 1989 , vol. 67, p. 1541 - 1549

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被引用次数: 41

摘要

Rate constants for the abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals have been measured relative to the corresponding abstraction reaction from ethylene. The method is based on the effect on the rates of formation of methane and ethane of the addition of small quantities of the reactants to the thermal chain reactions of ethylene in the temperature range 650-770 K. Taking the following values of ...