Synthesis and Luminescence of Soluble m eso-Unsubstituted Tetrabenzo-and Tetranaphtho [2, 3] porphyrins

…, AV Cheprakov, SA Vinogradov

文献索引：Finikova, Olga S.; Cheprakov, Andrei V.; Vinogradov, Sergei A. Journal of Organic Chemistry, 2005 , vol. 70, # 23 p. 9562 - 9572

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被引用次数: 72

摘要

Syntheses of soluble tetrabenzoporphyrins (TBP) and tetranaphtho [2, 3] porphyrins (TNP), with multiple substituents in the conjugated aromatic rings but bearing no substituents in the meso-positions, is reported. Both types of porphyrins were obtained by direct aromatization of precursor porphyrins, annealed with either cyclohexene or dihydronaphthalene fragments. TBPs and TNPs possess powerful absorption bands in the near-infrared (λ= ...