Thermal decomposition of N-nitrosohydroxylamines. III. N-Benzoyl-N-nitroso-O-tert-butylhydroxylamine

TW Koenig, M Deinzer, JA Hoobler

文献索引：Koenig,T. et al. Journal of the American Chemical Society, 1971 , vol. 93, p. 938 - 944

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被引用次数: 25

摘要

Abstract: The decomposition products of N-benzoyl-N-nitroso-0-tert-butylhydroxylamine have been determined in a variety of nonpolar solvents. These products can be ascribed to the intervention of benzoyloxy-tert-butoxy radical pairs. rert-Butyl perbenzoate is one such product which is formed in yields which increase with increasing viscosity. Oxygen-1 8 labeling studies show that this product is formed with essentially complete randomization ...