Iron and manganese (III)-porphyrins as new applicable catalysts for selective oxidation of imines with urea-hydrogen peroxide

…, M Montazerozohori, M Moghadam…

文献索引：Karami, Bahador; Montazerozohori, Morteza; Moghadam, Majid; Farahi, Mahnaz Journal of Chemical Research, 2007 , # 5 p. 275 - 277

全文：HTML全文

被引用次数: 0

摘要

A variety of imines were oxidised with urea-hydrogen peroxide using iron (III) and manganese (III)-tetraphenyl-porphyrins [Fe (TPP) Cl],[Mn (TPP) Cl] and manganese (III)- octabromotetraphenyl porphyrin [Mn (TPPBr8) Cl] as catalysts. Experimental results showed the released urea from UHP acts as an axial ligand. These catalysts showed high selectivity in oxidation of imines to corresponding nitrones and oxaziridines at 0° C to room ...