Journal of Organometallic Chemistry

Photochemically generated silicon-carbon double-bonded intermidiates: II. Photolysis of aryldisilanes in the presence of dienes

M Ishikawa, T Fuchikami, M Kumada

文献索引：Ishikawa,M. et al. Journal of Organometallic Chemistry, 1976 , vol. 118, p. 139 - 153

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摘要

Abstract Photolysis of eight aryldisilanes in the presence of 1, 3-conjugated dienes (butadiene, isoprene and 2, 3-dimethylbutadiene) has been studied. All of the aryldisilanes bearing a hydrogen on an ortho carbon atom in the aryl ring reacted upon UV irradiation with the conjugated dienes to give o-silyl-substituted (3-butenylsilyl) arene derivatives in high yields. The 13 C and 1 H NMR, and mass spectroscopic studies of the products are ...