Thermochemical Study of 1-Acetyl Vinyl p-Nitrobenzoate: Vinyl Bond Enthalpy in Captodative Olefins

…, R Herrera, J Tamariz

文献索引：Andrade; Munoz; Tamariz Synthetic Communications, 1992 , vol. 22, # 11 p. 1603 - 1609

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摘要

Captodative olefins are highly reactive and selective substrates in Diels–Alder and 1,3-dipolar cycloadditions. Seeking an explanation of this fact based on molecular energetics, the thermochemical analysis of 1-acetyl vinyl p-nitrobenzoate, a captodative olefin, has been performed using