Selective Isomerization of Epoxides to Allylic Alcohols Catalyzed by TiO2??Supported Gold Nanoparticles

C Raptis, H Garcia, M Stratakis

文献索引：Raptis, Christos; Stratakis, Manolis; Garcia, Hermenegildo Angewandte Chemie, International Edition, 2009 , vol. 48, # 17 p. 3133 - 3136

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被引用次数: 62

摘要

Abstract ReacTiO 2 ns for rings: Gold nanoparticles supported on TiO 2 are used as a novel heterogeneous catalyst for the isomerization of epoxides to allylic alcohols by a concerted mechanism (see scheme). The reaction proceeds in high yields and the product selectivity is often remarkable.

~88%

~95%

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