Synthesis of 1, 3-difunctionalized amine derivatives through selective CH bond oxidation

…, PM Wehn, J Chow, J Du Bois

文献索引：Espino; Wehn; Chow; Du Bois Journal of the American Chemical Society, 2001 , vol. 123, # 28 p. 6935 - 6936

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被引用次数: 359

摘要

Amination reactions of saturated CH bonds hold great potential as methods for the synthesis of amines and amine derivatives. 1, 2 We have recently delineated one such process that makes possible the conversion of 1 carbamates to oxazolidin-2-ones using dinuclear Rh carboxylate catalysis. 2 Further explorations of this chemistry have guided us to sulfamate esters 1 (Figure 1). This uniquely reactive class of compounds affords sixmembered ring ...