Amination reactions of saturated CH bonds hold great potential as methods for the synthesis of amines and amine derivatives. 1, 2 We have recently delineated one such process that makes possible the conversion of 1 carbamates to oxazolidin-2-ones using dinuclear Rh carboxylate catalysis. 2 Further explorations of this chemistry have guided us to sulfamate esters 1 (Figure 1). This uniquely reactive class of compounds affords sixmembered ring ...
