Total synthesis of (±)-β-bulnesene,(±)-cryptofauronol,(±)-fauronyl acetate, and (±)-valeranone

PG Sammes, LJ Street

文献索引：Sammes, Peter G.; Street, Leslie J. Journal of the Chemical Society, Chemical Communications, 1983 , # 12 p. 666 - 668

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被引用次数: 28

摘要

A versatile method for the preparation of perhydroazulenes and cis-fused 1 -decalones is described and exemplified by the synthesis of the title compounds. ... In a recent communication1 we have described the preparation of epoxy-bridged perhydroazulenes, of the type (1), by the intramolecular cycloaddition of isolated olefinic bonds to 3- oxidopyrylium species, themselves generated under mild conditions from the corresponding pyranulose acetates.a In order to use ...