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Supramolecular Tetrad of Subphthalocyanine–Triphenylamine–Zinc Porphyrin Coordinated to Fullerene as an “Antenna??Reaction??Center” Mimic: Formation of a …

…, DK Ju, KY Kay, F D'Souza, S Fukuzumi

文献索引:El-Khouly, Mohamed E.; Ju, Dong Kyu; Kay, Kwang-Yol; D'Souza, Francis; Fukuzumi, Shunichi Chemistry - A European Journal, 2010 , vol. 16, # 21 p. 6193 - 6202

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被引用次数: 77

摘要

Abstract We report here the formation of a long-lived charge-separated state of a self- assembled donor–acceptor tetrad, formed by axial coordination of a fulleropyrrolidine appended with an imidazole coordinating ligand (C 60 Im) to the zinc center of a subphthalocyanine–triphenylamine–zinc porphyrin (SubPc–TPA–ZnP), as a charge- stabilizing antenna reaction center mimic in toluene. The subphthalocyanine and ...