The development of a new nitrating agent: the unusual regioselective nitration of diphenylpolyethylene glycols and phenylpolyethylene glycols with (trimethylsilyl) …

…, K Kajita, N Onoda, S Morosawa

文献索引：Kimura, Masaru; Kajita, Kazushige; Onoda, Naoyuki; Morosawa, Shiro Journal of Organic Chemistry, 1990 , vol. 55, # 16 p. 4887 - 4892

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被引用次数: 27

摘要

'Concentration of substrate, TMSN, and Lewis acid is 0.017, 0.051, and 0.10 mmol, respectively. o/p ratio is calculated as fol-lows. bo/p= I (yield)/g (yield)= 8/9.'o/p= 9/10. d~/~= 11/12.'o/p= 13/14. fo/p= 15/16. 8o/p= 17/18. substrates possess a side chain that has several arranged oxygen atoms, the question arises whether nitronium ions might be collected along the chain symbolized in A, for the