Reaction of trimethylsilyl phosphites with functionalyzed aromatic aldehydes

AA Prishchenko, MV Livantsov, OP Novikova…

文献索引：Prishchenko; Livantsov; Novikova; Livantsova; Maryashkin Russian Journal of General Chemistry, 2005 , vol. 75, # 12 p. 1965 - 1967

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被引用次数: 2

摘要

Bis (trimethylsilyl)[(4-fluorophenyl)(trimethylsiloxy) methyl] phosphonate (Ia). To a solution of 10.7 g of tris (trimethylsilyl) phosphite in 30 ml of methylene chloride, a solution of 3.7 g of 4- fluorobenzaldehyde in 10 ml of methylene chloride was added dropwise with stirring at 10oC. The reaction mixture was stirred for 0.5 h and heated to boil. The solvent was removed, and the residue was distilled in a vacuum to give 10.5 g of phosphonate Ia, yield ...