Stereoselective Transformation of Enantiopure Cyclohexenol into cis-Hydrindan. An Enantioselective Formal Total Synthetic Route to (+)-Pumiliotoxin C

…, T Asoh, M Matsuura, K Fukumoto

文献索引：Toyota, Masahiro; Matsuura, Masaki; Fukumoto, Keiichiro Heterocycles, 1995 , vol. 41, # 4 p. 661 - 664

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被引用次数: 32

摘要

Pumiliotoxin C (1) 1 was originally isolated from the skin extracts of Dendrobates pumilio (a striking colored Panamanian poison arrow frog2). X-ray analysis3 of the crystalline hydrochloride of 1 established the structure, and the absolute configuration (2S, 4aS, 5R,