Australian Journal of Chemistry

Reactions of cyclohexadienes. X. Some dichlorocarbene adducts of alkoxycyclohexa-1, 4-dienes and their conversion into hydroxycyclopropanes and …

AJ Birch, R Keeton

文献索引：Birch,A.J.; Keeton,R. Australian Journal of Chemistry, 1971 , vol. 24, p. 331 - 341

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被引用次数: 8

摘要

Abstract Some reactions of dichlorocarbene adducts of alkoxycyclohexa-1, 4-dienes have been examined. The tetrahydropyranyl ethers lead to dichlorohydroxycyolopropanes, which often undergo ready ring fission to give initially chlorocycloheptenones. Bis-adducts can produce cyclooctane derivatives. β-(2?-Pyranyloxy)-1, 4, 5, 8-tetra-hydronaphthalenes give rise with dichlorocarbene to bis-or tris-adducts in which one cyclopropane ring can be ...