Abstract Tricarbonyl (6-hydroxy-2, 4-cycloheptadien-1-one) iron derived from tricarbonyl (tropone) iron was easily oxidized to give tricarbonyl (2, 4-cycloheptadiene-1, 6-dione) iron. This procedure was also extended to tricarbonyl (2-substituted tropone) iron and exo (bicyclo [5.1. O] octa-3, 5-dien-2-one) tricarbonyliron to yield tricarbonyl (2-substituted 2, 4- cycloheptadiene-1, 6-dione) iron and tricarbonyl (2, 4-cyclooctadiene-1, 6-dione) iron, ...