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Polycyclic fluoranthene hydrocarbons. Part 4. Electrophilic substitution of polycyclic fluoranthene hydrocarbons

M Minabe, BP Cho, RG Harvey

文献索引:Minabe, Masahiro; Cho, Bongsup P.; Harvey, Ronald G. Journal of the American Chemical Society, 1989 , vol. 111, # 11 p. 3809 - 3812

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被引用次数: 20

摘要

Abstract: The first systematic study of the sites of electrophilic substitution (acylation and/or bromination) of polycyclic fluoranthene hydrocarbons is described. The hydrocarbons studied include indeno [1, 2, 3-cd] pyrene (l), benz [a] aceanthrylene (2), benz [e] acephenanthrylene (3), and indeno [1, 2, 3-hi] chrysene (4). Compounds 1-4 all undergo bromination regioselectively in a single site. The latter are determined by conversion of ...