Catecholate LMCT bands as probes for the active sites of nonheme iron oxygenases

…, SJ Benkovic, LM Bloom, FC Bradley…

文献索引：Cox, D. D.; Benkovic, S. J.; Bloom, L. M.; Bradley, F. C.; Nelson, M. J.; et al. Journal of the American Chemical Society, 1988 , vol. 110, # 7 p. 2026 - 2032

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被引用次数: 202

摘要

Conclusions The results of this study show that state-of-the-art'H CRAMPS NMR techniques, including various kinds of relaxation experiments, are capable not only of distinguishing structurally different types of hydroxyl moieties on a silica surface but also of addressing the issue of proximity of one type relative to the others. Two distinctly different types of silanol groups are identified, and it is found that the hydrogen-bonded types are the ones that are ...