Tetrahedron

Cobalt-and rhodium-catalyzed cross-coupling reaction of allylic ethers and halides with organometallic reagents

H Yasui, K Mizutani, H Yorimitsu, K Oshima

文献索引：Yasui, Hiroto; Mizutani, Keiya; Yorimitsu, Hideki; Oshima, Koichiro Tetrahedron, 2006 , vol. 62, # 7 p. 1410 - 1415

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被引用次数: 48

摘要

Reactions of 2-alkenyl methyl ether with phenyl, trimethylsilylmethyl, and allyl Grignard reagents in the presence of cobalt (II) complexes are discussed. The success of the reactions heavily depends on the combination of the substrate, ligand, and Grignard reagent. In the reaction of cinnamyl methyl ether, the formation of the linear coupling products predominates over that of the relevant branched products. In the cobalt-catalyzed ...