Journal of the American Chemical Society

The Rearrangement of Allyl Groups in Three-carbon Systems. IV. Hydrocarbons

H Levy, AC Cope

文献索引：Levy; Cope Journal of the American Chemical Society, 1944 , vol. 66, p. 1687

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被引用次数: 40

摘要

The allyl-type group has been shown to undergo inversion in two such cases, as indicated in the equation. 2 This fact, together with first-order reaction kinetics and the observation that no interchange of migrating groups occurs when a mixture of two such compounds is heated, indicates that the rearrangement proceeds by an intramolecular cyclic mechanism. The influence of the groups, X and Y, is presumed to be derived from electron attraction, ...