A quick, efficient, one-pot method for the synthesis of substituted N-aryl lactams through the reaction of various kinds of corresponding substituted arenes with a variety of ω-azido alkanoic acid chlorides using a Lewis acid (ie EtAlCl2) at room temperature, through the in situ involvement of a Friedel–Crafts reaction followed by intramolecular Schimdt rearrangement was developed, and afforded good to excellent yields.