Synthetic communications

Catalytic olefin epoxidation with molecular oxygen over supported amidate-bridged platinum blue complexes

W Chen, J Yamada, K Matsumoto

文献索引：Chen, Wanzhi; Yamada, Jun; Matsumoto, Kazuko Synthetic Communications, 2002 , vol. 32, # 1 p. 17 - 22

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被引用次数: 6

摘要

ABSTRACT The platinum complexes,[Pt4 (NH3) 8 ((CH3) 3CCONH) 4]-(NO3) 5 and [Pt2 (NH3) 4 ((CH3) 3CCONH) 2](NO3) 4, supported on a surface of silica gel, Al2O3, activated carbon, and poly-(4-vinylpyridine) are active heterogeneous catalysts for the liquid phase epoxidation of various olefins under 1 atm of dioxygen in the presence of isobutyraldehyde.