A highly active protonated tetranuclear peroxotungstate for oxidation with hydrogen peroxide

R Ishimoto, K Kamata, N Mizuno

文献索引：Ishimoto, Ryo; Kamata, Keigo; Mizuno, Noritaka Angewandte Chemie - International Edition, 2012 , vol. 51, # 19 p. 4662 - 4665

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被引用次数: 40

摘要

Selective oxygen transfer to organic substrates with H2O2 as a terminal oxidant is important in industrial and synthetic chemistry because of the high content of active oxygen species in H2O2 and coproduction of only water. Therefore, a large number of complexes of titanium, vanadium, iron, manganese, tungsten, rhenium, and platinum have been developed for catalytic oxidation of various kinds of organic substrates with H2O2.[1–4] Among these ...