Chemistry Letters

Anion radical-induced desilylation of organosilane. Reactions of benzylsilanes with aldehydes and related compounds in the presence of butyllithium or lithium metal

S Kanemasa, J Tanaka, H Nagahama, O Tsuge

文献索引：Kanemasa, Shuji; Tanaka, Junji; Nagahama, Hideki; Tsuge, Otohiko Chemistry Letters, 1985 , p. 1223 - 1226

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被引用次数: 2

摘要

By the action of butyllithium or lithium metal in such polar aprotic solvent as DMF or HMPA in the presence of aldehydes or related compounds, some benzylsilanes suffer from anion radical-induced desilylation forming benzyl carbanions which add to the aldehydes and related compounds.