Journal of organometallic chemistry

One-pot palladium-catalyzed phosphination of aryl iodides with Ph 2 PSnR 3

SE Martı́n, M Bonaterra, RA Rossi

文献索引：Martin Sandra E., E.; Bonaterra, Mariana; Rossi, Roberto A. Journal of Organometallic Chemistry, 2002 , vol. 664, # 1-2 p. 223 - 227

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被引用次数: 6

摘要

We found a very efficient one-pot phosphination reaction starting with Ph3P, which by reaction with Na metal in liquid ammonia gives Ph2P− ions that reacted with R3SnCl to afford (trialkylstannyl) diphenylphosphine. The palladium-catalyzed coupling reaction of these stannanes with aryl iodides yield functionalized phosphines in high yield (69–97%). The use of Ph3P as starting reagent, the endurance of the reaction to a wide variety of ...