Synlett

A Photoirradiative Phase-Vanishing Method: Efficient Generation of HBr from Alkanes and Molecular Bromine and Its Use for Subsequent Radical Addition to Terminal …

H Matsubara, M Tsukida, D Ishihara, K Kuniyoshi…

文献索引：Matsubara, Hiroshi; Tsukida, Masaaki; Ishihara, Daisuke; Kuniyoshi, Kenji; Ryu, Ilhyong Synlett, 2010 , # 13 p. 2014 - 2018

全文：HTML全文

被引用次数: 2

摘要

Abstract A triphasic phase-vanishing (PV) system comprised of an alkane, perfluorohexanes, and bromine was successfully combined by photoirradiation to efficiently generate hydrogen bromide, which underwent radical addition with 1-alkenes in the hydrocarbon layer to afford terminal bromides in high yields.