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Organic letters

Copper-Catalyzed Tandem Oxidation− Olefination Process

M Davi, H Lebel

文献索引:Davi, Michael; Lebel, Helene Organic Letters, 2009 , vol. 11, # 1 p. 41 - 44

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被引用次数: 43

摘要

A novel catalytic sequence aerobic oxidation− olefination has been developed. A single and inexpensive copper catalyst provides a large range of olefins from alcohols in good to excellent yields. The reaction exhibits excellent functional group compatibility, and the nonbasic reaction conditions allow the transformation of chiral substrates without racemization.