Catalysis today

Catalytic performance of a boron peroxotungstate complex under homogeneous and heterogeneous conditions

ICMS Santos, SS Balula, MMQ Simões, L Cunha-Silva…

文献索引：Santos, Isabel C.M.S.; Balula, Salete S.; Simoes, Mario M.Q.; Cunha-Silva, Luis; Neves, M. Graca P.M.S.; De Castro, Baltazar; Cavaleiro, Ana M.V.; Cavaleiro, Jose A.S. Catalysis Today, 2013 , vol. 203, p. 87 - 94

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被引用次数: 7

摘要

The preparation and characterization (FT-IR, FT-Raman, 11B MAS NMR, diffuse reflectance, elemental analysis) of a novel boron peroxotungstate (BTBA) 4H [BW4O24](BTBA= benzyltributylammonium) is reported, along with its use in the homogeneous oxidation of cis- cyclooctene, geraniol, linalool and (−)-carveol with H2O2 as oxidant and acetonitrile as solvent. High catalytic activity was registered for all the substrates studied under ...

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