Photolysis of (3-Methyl-2 H-azirin-2-yl)-phenylmethanone: Direct Detection of a Triplet Vinylnitrene Intermediate

…, C Bohne, BS Ault, AD Gudmundsdottir

文献索引：Ranaweera, Ranaweera A. A. Upul; Zhao, Yu; Muthukrishnan, Sivaramakrishnan; Keller, Christopher; Gudmundsdottir, Anna D. Australian Journal of Chemistry, 2010 , vol. 63, # 12 p. 1645 - 1655

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被引用次数: 19

摘要

The photoreactivity of (3-methyl-2 H-azirin-2-yl)-phenylmethanone, 1, is wavelength- dependent (Singh et al. J. Am. Chem. Soc. 1972, 94, 1199− 1206). Irradiation at short wavelengths yields 2P, whereas longer wavelengths produce 3P. Laser flash photolysis of 1