Direct Route to 1, 3??Diketones by Palladium??Catalyzed Carbonylative Coupling of Aryl Halides with Acetylacetone

…, DU Nielsen, RH Taaning, AT Lindhardt…

文献索引：Korsager, Signe; Nielsen, Dennis U.; Taaning, Rolf H.; Lindhardt, Anders T.; Skrydstrup, Troels Chemistry - A European Journal, 2013 , vol. 19, # 52 p. 17687 - 17691

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被引用次数: 15

摘要

The development of new synthetic protocols for accessing 1, 3-diketones is always of high interest, as such structural motifs represent excellent platforms or advanced building blocks for the preparation of a number of heterocyclic compounds of pharmaceutical and agrochemical interest.[1] Traditionally, the synthesis of 1, 3-diketones relies on an aldol reaction between a carbonyl compound and an enolate followed by oxidation of the ...