Electron transfer processes. 31. Coupling of enolates of phenones with 2-chloro-2-nitropropane

GA Russell, B Mudryk, M Jawdosiuk…

文献索引：Russel, Glen A.; Mudryk, Boguslaw; Jawdosiuk, Mikolaj; Wrobel, Zbigniew Journal of Organic Chemistry, 1982 , vol. 47, # 10 p. 1879 - 1884

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被引用次数: 23

摘要

Lithium enolates of acetophenone, a-methoxyacetophenone, propiophenone, meta-or para- substituted propiophenonea, butyrophenone, isovalerophenone, 1-phenyl-1-hexanone, 1- indanone, 1-tetralone, or 1-benzosuberone react with 2-chloro-2-nitropropane in THF by free radical chain processes to produce ArCOCH (CMe2N02) R or ArCOC (R)= CMe2 and when R# H the product of oxidative dimerization,[ArCOC (R)-I2. The enolate anion of ...