Chiral fluorous phosphorus ligands based on the binaphthyl skeleton: synthesis and applications in asymmetric catalysis

J Bayardon, M Cavazzini, D Maillard, G Pozzi…

文献索引：Bayardon, Jerome; Cavazzini, Marco; Maillard, David; Pozzi, Gianluca; Quici, Silvio; Sinou, Denis Tetrahedron Asymmetry, 2003 , vol. 14, # 15 p. 2215 - 2224

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被引用次数: 37

摘要

Two enantiopure fluorous phosphines have been conveniently synthesized by combining palladium-catalyzed coupling reactions of easily available binaphthyl building-blocks with the introduction of fluorous ponytails onto aromatic compounds via ether bond formation. These new fluorous chiral phosphines have been tested as ligands in metal-catalyzed asymmetric transformations, the best results being obtained in the palladium-catalyzed ...