Tetrahedron letters

Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

WT Boese, AS Goldman

文献索引：Boese, William T.; Goldman, Alan S. Tetrahedron Letters, 1992 , vol. 33, # 16 p. 2119 - 2122

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被引用次数: 27

摘要

Abstract Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20–80 atm). In the presence of CCl 4, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.