Lipophilic Metal− Salicylideneimine− Crown Ether Hybrids—Ditopic Carriers in the Facilitated Transport of Amphiphilic Molecules Across Bulk Liquid Membranes

…, DT Rosa, D Coucouvanis

文献索引：Pike, Jay D.; Rosa, Dell T.; Coucouvanis, Dimitri European Journal of Inorganic Chemistry, 2001 , # 3 p. 761 - 777

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被引用次数: 15

摘要

Abstract The crown ether-functionalized Mn III salicylaldimine complexes manganese (III) 4, 5-bis (3, 5-di-tert-butylsalicylideneimine) benzo-18-crown-6-X [X= Cl−, I−, CH 3 COO−,(CH 3) 3 CCOO−, B (Ph) 4−] have recently been synthesized and studied as effective ditopic transport carriers of hydrophobic amino acids and neurotransmitters through CHCl 3 bulk liquid membranes (BLMs). A detailed analysis of the BLM transport of tryptophan and ...