Tetrahedron Letters

Catalytic regioselective dehydrogenation of unsymmetrical α, ω-diols using ruthenium complexes

Y Ishii, K Osakada, T Ikariya, M Saburi, S Yoshikawa

文献索引：Ishii, Youichi; Osakada, Kohtaro; Ikariya, Takao; Saburi, Masahiko; Yoshikawa, Sadao Tetrahedron Letters, 1983 , vol. 24, # 26 p. 2677 - 2680

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被引用次数: 16

摘要

Abstract Ruthenium complex catalyzed regioselective dehydrogenation of unsymmetrically substituted 1, 4-and 1, 5-diols in the presence of α, β-unsaturated ketone as a hydrogen acceptor and triethylamine gave β-substituted γ-lactones and γ-substituted δ-lactones as major products, respectively.