Palladium (II)-catalyzed oxidation of alcohols to aldehydes and ketones by molecular oxygen

T Nishimura, T Onoue, K Ohe…

文献索引：Nishimura, Takahiro; Onoue, Tomoaki; Ohe, Kouichi; Uemura, Sakae Journal of Organic Chemistry, 1999 , vol. 64, # 18 p. 6750 - 6755

全文：HTML全文

被引用次数: 420

摘要

A novel combination of Pd (OAc) 2/pyridine/MS3A catalyzes the aerobic oxidation in toluene of a variety of primary and secondary alcohols into the corresponding aldehydes and ketones in high yields. Various substituents and protecting groups are compatible with this oxidation. The ca. 2: 3 ratio of O2 uptake to product yield is observed, whereas in the absence of MS3A, the ratio is ca. 1: 1, suggesting the in situ formation of H2O2 and its ...

~80%

Synthesis of 5??, 6??, 7??and 18??mono??13C??labelled retina...

[Courtin, J. M. L.; 't Lam, G. K.; Peters, A. J. M.; Lugtenburg, J. Recueil des Travaux Chimiques des Pays-Bas, 1985 , vol. 104, # 11 p. 281 - 288]

Synthesis of 3-deazathiamine

[Hawksley, Daniel; Griffin, David A.; Leeper, Finian J. Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 2 p. 144 - 148]

Solvents of Low Nucleophilicity. VIII. Possible Vinyl Cation...

[Peterson,P.E.; Duddey,J.E. Journal of the American Chemical Society, 1966 , vol. 88, p. 4990 - 4996]

Mechanistic and synthetic aspects of the acid-catalysed hydr...

[Scheeren, J. W.; Bakker, C. G.; Peperzak, R.; Nivard, R. J. F. Tetrahedron Letters, 1987 , vol. 28, # 16 p. 1821 - 1824]

Uv-light-and radiation-initiated addition of acetaldehyde to...

[Liska, Frantisek; Valenta, Miroslav; Fikar, Jiri; Jandova, Martina; Pesek, Miroslav; Trska, Petr Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 6 p. 1287 - 1296]