Electronic and magnetic metal–metal interactions in dinuclear oxomolybdenum (V) complexes across bis-phenolate bridging ligands with different spacers between …

…, ZR Bell, JC Jeffery, JA McCleverty, MD Ward…

文献索引：Bayly; Humphrey; De Chair; Paredes; Bell; Jeffery; McCleverty; Ward; Totti; Gatteschi; Courric; Steele; Screttas Journal of the Chemical Society, Dalton Transactions, 2001 , # 9 p. 1401 - 1414

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被引用次数: 11

摘要

A series of dinuclear complexes has been prepared in which two {MoV (TpMe, Me)(O) Cl} fragments (abbreviated as Mo; TpMe, Me= tris (3, 5-dimethylpyrazol-1-yl) hydroborate) are attached to either end of a bis-p-phenolate bridging ligand [(4, 4′-OC6H4)–X–(4, 4′- C6H4O)] 2−. The complexes are Mo2 (CC)(X= CHCH), Mo2 (CC) 2 (X= CHCH–CHCH), Mo2 (CC) 3 (X= CHCH–CHCH–CHCH), Mo2 (th)(X= 2, 5-thiophenediyl), Mo2 (th) 2 (X= 2, 5: 2 ...